New mixed ligand complexes of some metal ions Zn(II), Cd(II) and Hg(II) were prepared by reacting with mixture of two bidentate ligands [ HL = (P-methyl anilino) –P– chloro phenyl acetonitrile and en = ethylene diamine] in a molar ratio of 1:1:1[ M : HL : en] in ethanol . The ligand HL was previously prepared by Strecker’s procedure which includes the reaction of p- toluidine with P- chlorobenzaldehyde in the presence of KCN in acidic medium. The structures of new compounds were identified by elemental analyses, atomic absorption and thermal analyses TG/DTG in addition to FTIR and U.V-VIS. Spectra. The electrical conductivity measurements of metal complexes were also determined. From the obtained data the octahedral structure was suggested for all prepared complexes.
Preparation and Characterization of New Mixed Ligand Complexes of (p-Methyl Anilino)-p-Chloro Phenyl Acetonitrile and Ethylene Diamine
veterinary drugs complexes of mixed ligand
(α – Aminonitrile & en) complexes
Zn (II)
Cd(II)) and Hg complexes