doi:10.21123/bsj.2016.13.2.2NCC.0048

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Publication Date

Sun Jun 05 2016

Journal Name

Baghdad Science Journal

Volume

13

Issue Number

2.2NCC

DOI

10.21123/bsj.2016.13.2.2NCC.0048

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Kinetic Model for Solute Diffusion in Liquid Membrane Systems

"kinetic model

diffusion

liquid membranes

mathematical model

solute diffusion in a LMS."

Juan Abdul-Wahid O.

Eman T.

Yousif I.

Taki A.

...Show More Authors

In this study, a mathematical model for the kinetics of solute transport in liquid membrane systems (LMSs) has been formulated. This model merged the mechanisms of consecutive and reversible processes with a “semi-derived” diffusion expression, resulting in equations that describe solute concentrations in the three sections (donor, acceptor and membrane). These equations have been refined into linear forms, which are satisfying in the special conditions for simplification obtaining the important kinetic constants of the process experimentally.

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Publication Date

Sat Sep 01 2018

Journal Name

Polyhedron

Novel dichloro (bis {2-[1-(4-methylphenyl)-1H-1, 2, 3-triazol-4-yl-κN3] pyridine-κN}) metal (II) coordination compounds of seven transition metals (Mn, Fe, Co, Ni, Cu, Zn and Cd)

The 1

3-dipolar cycloaddition “click” reaction between an azide and an alkyne to give a 1

2

3-triazole was reported by Huisgen in 1961 [1]. In 2002 the Copper(I)-catalyzed Azide-Alkyne Cycloaddition (CuAAC) to prepare a 1

2

3-triazole was reported [2]

[3]. The existence of relatively basic nitrogen atoms in the 1

2

3-triazole rings

and the possibility of introducing additional donor groups in the substituents (Fig. 1)

made the CuAAC “click” reaction an attractive method to prepare differently substituted 1

2

3-triazoles. These compounds have been used as ligands to coordinate to various metal ions that display a range of applications such as in electrochemical and photochemical studies

in supramolecular chemistry

magnetism

metal-ion sensing and catalysis [4]. The reasons for the success of the “click” reaction

is that it is easy to carry out and is widely applicable. It is not affected by a variety of functional groups

and can be carried out with a variety of Cu(I) catalysts and solvents

including aqueous conditions. The Cu(I) catalysts overcome the high activation energy barrier of the non-catalyzed Huisgen reaction by changing the mechanism of the reaction. A large variety of copper catalysts can be used for the CuAAC reaction

on condition that the maximum concentration of Cu(I) species is generated during the reaction. The pre-catalyst can be a Cu(II) salt (usually CuSO4) together with a reducing agent (often sodium ascorbate) or a Cu(I) compound in the presence of a base or amine ligand and a reducing agent to prevent oxidation to Cu(II). Some strong oxidising cupric salts or complexes such as Cu(OAc)2 also work. The solvent is very flexible from organic to aqueous

with the most commonly used combination water + an alcohol (t-BuOH

MeOH or EtOH). The key role of the solvent or solvent mixture is to solubilize the substrates and Cu(I) catalyst in order to ensure rapid reactions. Such aqueous conditions are very useful for biochemical conjugations

as well as for organic syntheses. We recently reported on the synthesis of a series of differently substituted 1

2

3-triazole chromophores

the substituted 2-(1-phenyl-1H-1

2

3-triazol-4-yl)pyridine ligands [5]

see Fig. 2 middle

with substituents R = H (L1)

CH3 (L2)

OCH3 (L3)

COOH

F

Cl

CN

CF3

O(CH2)3CH3 and N(CH3)2. These versatile ligands were found to coordinate to various first row transition metals

such as manganese

cobalt and nickel [6]. Here we extend the series to include more first row transition metal(II) coordination compounds

iron

copper and zinc

as well as a second row transition metal(II) coordination compound

cadmium

containing the 2-(1-(4-methyl-phenyl)-1H-1

2

3-triazol-1-yl)pyridine chromophore (Fig. 2 right with R = CH3). This series of seven novel coordination compounds is the first series of pyridyl-triazole based transition metal coordination compounds where seven different transition metals are coordinated to the same 1

2

3-triazole chromophore

namely 2-(1-(4-methyl-phenyl)-1H-1

2

3-triazol-1-yl)pyridine.

Kinaan M

...Show More Authors

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Publication Date

Fri Jan 31 2025

Journal Name

Мир русского слова

Лингвоориентированная методика преподавания русского языка как иностранного в арабской аудитории

РУССКИЙ ЯЗЫК КАК ИНОСТРАННЫЙ

АРАБСКИЕ СТУДЕНТЫ

ЛИНГВООРИЕНТИРОВАННАЯ МЕТОДИКА

RUSSIAN AS A FOREIGN LANGUAGE

ARAB STUDENTS

LINGVO-ORIENTED METHOD

Yaseen

...Show More Authors

Статья посвящена возможности использования в обучении русскому языку как иностранному лингвоориентированной методики для арабских студентов. Обосновывается термин «лингвоориентированная методика», предложенный В. Н. Вагнер, и на основе положений заявленной методики проводится сопоставление изучаемого (русского) языка с родным (арабским) языком обучающихся.

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Publication Date

Fri Jan 01 2021

Journal Name

Prepodavatel Xxi Vek

Enrichment of Vocabulary and the Formation of Grammatically Correct Speech of Foreign Students When Studying the Text of a Literary Work

enrichment of vocabulary

formation of grammatically correct speech of a foreign student

Russian literature

literary text

foreign audience.

Azzam Ahmed

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Publication Date

Tue Jun 01 2021

Journal Name

Int. J. Nonlinear Anal. Appl.

Fibrewise totally perfect mapping

Fibrewise totally topological space

filter base

totally converges

totally closed mapping

totally rigid a set

totally perfect mapping.

Y.Y.

...Show More Authors

The main purpose of this paper is to introduce a some concepts in fibrewise totally topological space which are called fibrewise totally mapping, fiberwise totally closed mapping, fibrewise weakly totally closed mapping, fibrewise totlally perfect mapping fibrewise almost totally perfect mapping. Also the concepts as totally adherent point, filter, filter base, totally converges to a subset, totally directed toward a set, totally rigid, totally-H-set, totally Urysohn space, locally totally-QHC totally topological space are introduced and the main concept in this paper is fibrewise totally perfect mapping in totally top

Publication Date

Sat Jan 01 2022

Journal Name

Technologies And Materials For Renewable Energy, Environment And Sustainability: Tmrees21gr

AIP Conference Proceedings 2437, 020060 (2022); https://doi.org/10.1063/5.0092690 2437, 020060© 2022 Author(s).Theoretical calculation of the electroniccurrent at N3 contact with TiO2 solar celldevices (3) (PDF) Theoretical calculation of the electronic current at N 3 contact with TiO 2 solar cell devices ARTICLES YOU MAY BE INTERESTED IN Theoretical studies of electronic transition characteristics of senstizer molecule dye N3-SnO 2 semiconductor interface AIP Conference. Available from: https://www.researchgate.net/publication/362813854_Theoretical_calculation_of_the_electronic_current_at_N_3_contact_with_TiO_2_solar_cell_devices_ARTICLES_YOU_MAY_BE_INTERESTED_IN_Theoretical_studies_of_electronic_transition_characteristics_of_senstiz [accessed May 01 2023].

Theoretical calculation

electronic current

N 3 - TiO 2 solar cell

Hadi J.

...Show More Authors

Theoretical calculation of the electronic current at N 3 contact with TiO 2 solar cell devices ARTICLES YOU MAY BE INTERESTED IN Theoretical studies of electronic transition characteristics of senstizer molecule dye N3-SnO 2 semiconductor interface AIP Conference. Available from: https://www.researchgate.net/publication/362813854_Theoretical_calculation_of_the_electronic_current_at_N_3_contact_with_TiO_2_solar_cell_devices_ARTICLES_YOU_MAY_BE_INTERESTED_IN_Theoretical_studies_of_electronic_transition_characteristics_of_senstiz [accessed May 01 2023].

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(2)

Publication Date

Sat Dec 01 2012

Journal Name

Iraqi Journal Of Physics

Elastic electron scattering from some 2s-1d shell nuclei

charge density distributions

elastic electron scattering form factors

Even- A 2s 1d shell nuclei

root mean square charge radii

Altaf Abdul Majeed

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The charge density distributions (CDD) and the elastic electron
scattering form factors F(q) of the ground state for some even mass
nuclei in the 2s 1d shell ( Ne Mg Si 20 24 28 , , and S 32 ) nuclei have
been calculated based on the use of occupation numbers of the states
and the single particle wave functions of the harmonic oscillator
potential with size parameters chosen to reproduce the observed root
mean square charge radii for all considered nuclei. It is found that
introducing additional parameters, namely 1 , and , 2  which
reflect the difference of the occupation numbers of the states from
the prediction of the simple shell model leads to a remarkable
agreement between the calculated an

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Publication Date

Fri Jul 01 2016

Journal Name

Journal Of Engineering

Study the Properties of Sodium Silicate Composite as a Barrier Separating Between the Internal Oil Distillation Towers and Chemical Fumes of Crude Oil

Sodium Silicate Composite as a Barrier Separating Between the Internal Oil Distillation Towers and Chemical Fumes of Crude Oil

سلام حسين

رولا عبد الخضر

سجى اياد

...Show More Authors

The study of surface hardness, wear resistance, adhesion strength, electrochemical corrosion resistance and thermal conductivity of coatings composed from sodium silicate was prepared using graphite micro-size particles and carbon nano particles as fillers respectively of concentration of (1-5%), for the purpose of covering and protecting the oil distillation towers. The results showed that the sodium silicate coating reinforced with carbon nano-powder has higher resistance to stitches, mechanical wear, adhesive and thermal conductivity than graphite/sodium silicate composite especially when the ratio 5% and 1%, the electrochemical corrosion test confirmed that the coating process of stainless steel 304 lead to increasin

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Publication Date

Mon Apr 23 2018

Journal Name

Elibrary.ru

PHYSICAL FITNESS OF FEMALE STUDENTS FROM IRAQ AND RUSSIA: COMPARATIVE ANALYSIS

PHYSICAL FITNESS

FEMALE STUDENTS FROM RUSSIA AND IRAQ

MOBILITY IN JOINTS

COORDINATION ABILITIES

STATIC ENDURANCE

Nazik Subhi

...Show More Authors

Objective of the study was to rate and analyze the physical fitness of female students from Iraq and Russia to find similarities, differences and regularities. Sampled for the study were 44 female non-sporting students: 20 students from Pedagogical University in Bagdad; and 24 students from Russian State University of Physical Education, Sport, Youth and Tourism in Moscow. The study was designed to obtain the joints flexibility, coordination, speed-strength and static endurance rates. The Iraqi students were tested with higher coordination abilities than their Russian peers, whilst the latter were ranked higher in the speed-strength, shoulder joints and spine flexibility tests, albeit lower than their Iraqi peers in the hip flexibility test

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Publication Date

Mon Sep 16 2019

Journal Name

Ibn Al-haitham Journal For Pure And Applied Sciences

Pseudo Primary-2-Absorbing Submodules and Some Related Concepts

Primary submodules

pseudo-2-absorbing submodules

pseudo primary-2-absorbing submodules

multiplication modules

non-singular modules

socle of a modules.

Omar A.

Haibat K.

...Show More Authors

Let be a commutative ring with identity. The aim of this paper is introduce the notion of a pseudo primary-2-absorbing submodule as generalization of 2-absorbing submodule and a pseudo-2-absorbing submodules. A proper submodule of an -module is called pseudo primary-2-absorbing if whenever , for , , implies that either or or . Many basic properties, examples and characterizations of these concepts are given. Furthermore, characterizations of pseudo primary-2-absorbing submodules in some classes of modules are introduced. Moreover, the behavior of a pseudo primary-2-absorbing submodul

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Publication Date

Fri Jan 01 2016

Journal Name

International Journal Of Advanced Scientific And Technical Research

Topological Generalizations of Rough Concepts

Digraph

Out-degree sets

In-degree sets

Topological spaces

Subbase

Rough sets

Rough approximations

Rough measures

Y. Y.

...Show More Authors

The importance of topology as a tool in preference theory is what motivates this study in which we characterize topologies generating by digraphs. In this paper, we generalized the notions of rough set concepts using two topological structures generated by out (resp. in)-degree sets of vertices on general digraph. New types of topological rough sets are initiated and studied using new types of topological sets. Some properties of topological rough approximations are studied by many propositions.

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