The main objective of this thesis is to study new concepts (up to our knowledge) which are P-rational submodules, P-polyform and fully polyform modules. We studied a special type of rational submodule, called the P-rational submodule. A submodule N of an R-module M is called P-rational (Simply, N≤_prM), if N is pure and Hom_R (M/N,E(M))=0 where E(M) is the injective hull of M. Many properties of the P-rational submodules were investigated, and various characteristics were given and discussed that are analogous to the results which are known in the concept of the rational submodule. We used a P-rational submodule to define a P-polyform module which is contained properly in the polyform module. An R-module M is called P-polyform if every essential submodule of M is P-rational in M. We study this kind of module in some detail and introduced some characterizations of the P-polyform module and its relationships with some other modules. The third kind of module in this thesis is called fully polyform module, and it is contained in the class of polyform module. A module M is said to be fully polyform, if every P-essential submodule of M is rational in M, that is Hom_R(M/N, E(M))=0 for every P-essential submodule N of M. In fact, the class of fully polyform modules lies between polyform modules and essentially quasi-Dedekind modules. The main characteristics of fully polyform modules were investigated, and some characterizations of these types of modules were established. Furthermore, the relationships between this class and other related modules were examined.